Triethylamine → Dimethyldiphenylmethane

HRID 2081290ノート

反応式

HRID 2081290 の反応式
CS(O[C:6]1[CH:11]=[CH:10][C:9]([C:12]([C:15]2[CH:20]=[CH:19][C:18](OS(C)(=O)=O)=[CH:17][CH:16]=2)([CH3:14])[CH3:13])=[CH:8][CH:7]=1)(=O)=O.C(N(CC)CC)C>C(OCC)(=O)C.[Pd]>[C:9]1([C:12]([C:15]2[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=2)([CH3:14])[CH3:13])[CH:10]=[CH:11][CH:6]=[CH:7][CH:8]=1

参加物

5

反応物 2

HCID 8471TriethylamineHCID 148328252,2-Bis-(4-methylsulphonyloxy-phenyl)-propane

生成物 1

HCID 13065Dimethyldiphenylmethane収率 84%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒2 回HCID 8857Ethyl Acetate溶媒

実験手順

0.5 mol of Compound A were stirred at 40° C. and under 20 bar of H2 in 3,000 ml of ethyl acetate with the addition of 27 g of palladium/carbon (5% Pd) and 1 mol of triethylamine; during the course of the reaction a further 15 g of Pd/C were added in total. After distillation, 84% of Compound B was obtained.

後処理

  1. additionwere added in total
  2. distillationAfter distillation

出典と根拠

ORDレコード
ord-c7d3291c9bc2418294004ed97bea36fc
出典データセット
uspto-grants-1993_02
特許番号
US05183926

反応ノート

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