Peracetic Acid → 17-Ethyl-20-fluoro-1,14-dihydroxy-12-[2'-(4"-(6'"-tert-butyldimethylsilyloxynaphth-2-yloxy)-3"-methoxycyclohexyl)-1'-methylvinyl]-23,25-dimethoxy-13,19,21,27-tetra-methyl-11,28-dioxa-4-azatricyclo[22.3.1.04,9]-octacos-18-ene-2,3,10,16-tetraone

反応式

[Si](OC1C=C2C(=CC=1)C=C([Bi](C1C=CC3C(=CC=C(O[Si](C(C)(C)C)(C)C)C=3)C=1)C1C=[CH:28][C:27]3[C:22](=[CH:23][CH:24]=[C:25]([O:30][Si:31]([C:34]([CH3:37])([CH3:36])[CH3:35])(C)[CH3:32])[CH:26]=3)C=1)C=C2)(C(C)(C)C)(C)C.[C:56](OO)(=O)C.[CH2:61]1[CH2:65]OC[CH2:62]1.[CH2:66]([CH:68]1[CH:94]=[C:93]([CH3:95])[CH:92]([F:96])[CH:91]([CH3:97])[CH2:90][CH:89]([O:98][CH3:99])[CH:88]2[O:100][C:84]([OH:104])([CH:85]([CH3:103])[CH2:86][CH:87]2[O:101][CH3:102])[C:83](=[O:105])[C:82](=[O:106])[N:81]2[CH:76]([CH2:77][CH2:78][CH2:79][CH2:80]2)[C:75](=[O:107])[O:74][CH:73]([C:108]([CH3:119])=[CH:109][CH:110]2[CH2:115][CH2:114][CH:113]([OH:116])[CH:112]([O:117][CH3:118])[CH2:111]2)[CH:72]([CH3:120])[CH:71]([OH:121])[CH2:70][C:69]1=[O:122])[CH3:67]>C(Cl)Cl.CC([O-])=O.CC([O-])=O.[Cu+2]>[CH2:66]([CH:68]1[CH:94]=[C:93]([CH3:95])[CH:92]([F:96])[CH:91]([CH3:97])[CH2:90][CH:89]([O:98][CH3:99])[CH:88]2[O:100][C:84]([OH:104])([CH:85]([CH3:103])[CH2:86][CH:87]2[O:101][CH3:102])[C:83](=[O:105])[C:82](=[O:106])[N:81]2[CH:76]([CH2:77][CH2:78][CH2:79][CH2:80]2)[C:75](=[O:107])[O:74][CH:73]([C:108]([CH3:119])=[CH:109][CH:110]2[CH2:115][CH2:114][CH:113]([O:116][C:61]3[CH:65]=[CH:28][C:27]4[C:22](=[CH:23][CH:24]=[C:25]([O:30][Si:31]([C:34]([CH3:35])([CH3:37])[CH3:36])([CH3:32])[CH3:56])[CH:26]=4)[CH:62]=3)[CH:112]([O:117][CH3:118])[CH2:111]2)[CH:72]([CH3:120])[CH:71]([OH:121])[CH2:70][C:69]1=[O:122])[CH3:67]