Water → N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

HRID 2105290ノート

反応式

HRID 2105290 の反応式
[C:1]1([CH3:13])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9](Cl)(=[O:11])=[O:10].[CH3:14][C:15](=[N:17][OH:18])[CH3:16].O>N1C=CC=CC=1>[CH3:13][C:1]1[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[S:9]([O:18][N:17]=[C:15]([CH3:16])[CH3:14])(=[O:11])=[O:10]

参加物

5

反応物 3

HCID 962WaterHCID 130462-Mesitylenesulfonyl chlorideHCID 67180Acetone, oxime

生成物 1

HCID 279802N-[(2,4,6-Trimethylbenzene-1-sulfonyl)oxy]propan-2-imine

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

To a solution of mesitylenesulfonyl chloride (2.0 g, 9.05 mmol) in pyridine (30 mL) was added acetone oxime (0.67 g, 9.05 mmol), and the solution was stirred under N2 for 16 hours. It was poured into 500 ml of water and stirred for 1 hour. The precipitate was filtered and dried. Acetone O-(2,4,6-trimethylphenylsulfonyl)oxime was obtained as white powder (57.6%) yield.

後処理

  1. stirringstirred for 1 hour
  2. filtrationThe precipitate was filtered
  3. customdried

出典と根拠

ORDレコード
ord-8deaa3c6c49246ac97ccd16d5fb37fbf
出典データセット
uspto-grants-2009_08
特許番号
US07579340B2

反応ノート

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