Acrolein → 2-isobutoxy-3,4-dihydro-2H-pyran
反応式
[CH2:1]([O:5][CH:6]=[CH2:7])[CH:2]([CH3:4])[CH3:3].[CH:8]([CH:10]=[CH2:11])=[O:9]>C(C1C=CC(C)=C(O)C=1C(C)(C)C)(C)(C)C>[CH2:1]([O:5][CH:6]1[CH2:7][CH2:11][CH:10]=[CH:8][O:9]1)[CH:2]([CH3:4])[CH3:3]参加物
4
実験手順
In a 50 L-volume autoclave made of stainless-steel, 16.22 kg of isobutylvinylether (IBVE), 6.97 kg of acrolein (ACR) and 0.08 kg of di-t-butylhydroxytoluene (BHT) were placed and the inside of the reactor was purged with nitrogen. The pressure was increased to 3 MPa with nitrogen and reaction was performed at 135° C. for 16 hours. The yield of 3,4-dihydro-2-isobutoxy-2H-pyran (DHIBP) was 94% (with ACR used as standard). The reaction solution was subjected to distillation, to thereby obtain 17.1 kg of DHIBP (20 kPa/120° C.).
後処理
- customthe inside of the reactor was purged with nitrogen
- temperatureThe pressure was increased to 3 MPa with nitrogen and reaction
- distillationThe reaction solution was subjected to distillation
出典と根拠
- ORDレコード
- ord-ab04d9b7c37540418fd7a8b9f9ecdc4a
- 出典データセット
- uspto-grants-2009_04
- 特許番号
- US07518003B2
反応ノート
読み込み中…