Iodoethane → Methyl 2-ethyl-6-hydroxy-2,3-dihydrobenzofuran-2-carboxylate

反応式

C[O:2][C:3]1[CH:15]=[CH:14][C:6]2[CH:7]=[C:8]([C:10]([O:12][CH3:13])=[O:11])[O:9][C:5]=2[CH:4]=1.[CH2:16](I)[CH3:17]>>[CH3:13][O:12][C:10]([C:8]1([CH2:16][CH3:17])[CH2:7][C:6]2[CH:14]=[CH:15][C:3]([OH:2])=[CH:4][C:5]=2[O:9]1)=[O:11]

参加物

反応物 2

HCID 6340Iodoethane

HCID 3016964Methyl 6-methoxybenzofuran-2-carboxylate

生成物 1

HCID 11379051Methyl 2-ethyl-6-hydroxy-2,3-dihydrobenzofuran-2-carboxylate

実験手順

The title compound was prepared following the procedure described in Example 1, Step 1 employing methyl 6-methoxy-benzofuran-2-carboxylate instead of methyl 5-methoxy-benzofuran-2-carboxylate and ethyl iodide instead of methyl iodide.

出典と根拠

ORDレコード: ord-c742b24b37e44a569394a8292d94c07b
出典データセット: uspto-grants-2009_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07524882B2

反応ノート

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