Lithium bis((trifluoromethyl)sulfonyl)azanide → HCID 178483696、化合物

HRID 2116844

反応式

HRID 2116844 の反応式
[N-:1]([S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10])[S:2]([C:5]([F:8])([F:7])[F:6])(=[O:4])=[O:3].[Li+].[CH3:17][N:18]([C:20]([N:23]([CH3:25])[CH3:24])(Cl)[Cl:21])[CH3:19]>C(#N)C>[N-:1]([S:2]([C:5]([F:8])([F:6])[F:7])(=[O:4])=[O:3])[S:9]([C:12]([F:15])([F:14])[F:13])(=[O:11])=[O:10].[CH3:17][N:18]([C+:20]([N:23]([CH3:25])[CH3:24])[Cl:21])[CH3:19]

参加物

4

反応物 2

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanideHCID 125447451,1-Dichloro-N,N,N',N'-tetramethylmethanediamine

生成物 1

HCID 178483696HCID 178483696、化合物収率 98.8%

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒2 回

実験手順

0.84 g (2.92 mmol) of lithium bis(trifluoromethanesulfonyl)imide in 4 ml of acetonitrile are added with stirring at room temperature to a solution of 0.5 g (2.92 mmol) of bis(dimethylamino)dichloromethane in 4 ml of acetonitrile. The mixture is stirred for 12 hours, and the solid LiCl is subsequently filtered off. Acetonitrile is distilled off. The crystals formed are dried at 50° C. under a reduced pressure of 10.0 Pa, giving 1.2 g of bis(dimethylamino)chlorocarbenium bis(trifluoromethanesulfonyl)imide, corresponding to a yield of 98.8%.

後処理

  1. filtrationthe solid LiCl is subsequently filtered off
  2. distillationAcetonitrile is distilled off
  3. customThe crystals formed
  4. customare dried at 50° C. under a reduced pressure of 10.0 Pa

出典と根拠

ORDレコード
ord-6b823c7bcccd45fb84b20b90089e34af
出典データセット
uspto-grants-2008_10
特許番号
US07439395B2

関連ノート

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