Isopropanol → 2-ethyl-2-adamantyl Methacrylate p-acetoxystyrene

HRID 2121317

反応式

HRID 2121317 の反応式
[C:1]([O:6][C:7]1([CH2:17][CH3:18])[CH:14]2[CH2:15][CH:10]3[CH2:11][CH:12]([CH2:16][CH:8]1[CH2:9]3)[CH2:13]2)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20].C(O)(C)C.N(C(C)(C)C(OC)=O)=NC(C)(C)C(OC)=O>CC(C)=O.CO>[C:1]([O:6][C:7]1([CH2:17][CH3:18])[CH:8]2[CH2:16][CH:12]3[CH2:11][CH:10]([CH2:15][CH:14]1[CH2:13]3)[CH2:9]2)(=[O:5])[C:2]([CH3:4])=[CH2:3].[C:19]([O:22][C:23]1[CH:30]=[CH:29][C:26]([CH:27]=[CH2:28])=[CH:25][CH:24]=1)(=[O:21])[CH3:20]

参加物

7

反応物 4

HCID 3776Isopropanol2 回HCID 757631,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 758214-Ethenylphenyl acetateHCID 98136452-Ethyl-2-methacryloyloxyadamantane

生成物 1

HCID 865871472-ethyl-2-adamantyl Methacrylate p-acetoxystyrene

試薬・触媒・溶媒 2

HCID 180Acetone溶媒HCID 887Methanol溶媒

反応条件

温度
75 °C

実験手順

A flask was charged with 39.7 g (0.16 mol) of 2-ethyl-2-adamantyl methacrylate, 103.8 g (0.64 mol) of p-acetoxystyrene and 265 g of isopropanol, and the mixture was heated to 75° C. under the nitrogen atmosphere. To the obtained solution was dropped a solution prepared by dissolving 11.05 g (0.048 mol) of dimethyl 2,2′-azobis(2-methylpropionate) into 22.11 g of isopropanol. After keeping the solution for about 0.3 hour at a temperature of 75° C. and then with stirring for 12 hours, the solution was diluted with acetone, and then the reaction solution was poured into a large amount of methanol to have a polymer precipitated, followed by filtration. Amount of thus obtained copolymer of 2-ethyl-2-adamantyl methacrylate and p-acetoxystyrene was 250 g (note: that this is a weight of a wet cake containing methanol).

後処理

  1. additionTo the obtained solution was dropped a solution
  2. customprepared
  3. customfor about 0.3 hour
  4. customat a temperature of 75° C.
  5. customprecipitated
  6. filtrationfollowed by filtration
  7. additioncontaining methanol)

出典と根拠

ORDレコード
ord-29d0a6e462354c299fa6a201db7c9deb
出典データセット
uspto-grants-2004_02
特許番号
US06696218B2

関連ノート

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