Dichloromethane → 4-(3-(tert-butyldimethylsilyloxy)-alpha-chlorobenzyl)-N,N-diethylbenzamide

反応式

[C:5]([CH3:6])([CH3:7])([CH3:8])[Si:9]([O:10][c:11]1[cH:12][c:13]([CH:14]([OH:15])[c:16]2[cH:17][cH:18][c:19]([C:20](=[O:21])[N:22]([CH2:23][CH3:24])[CH2:25][CH3:26])[cH:27][cH:28]2)[cH:29][cH:30][cH:31]1)([CH3:32])[CH3:33].[Cl:34][CH2:35][Cl:36].[S:1]([Cl:2])([Cl:3])=[O:4]>>[Cl:3][CH:14]([c:13]1[cH:12][c:11]([O:10][Si:9]([C:5]([CH3:6])([CH3:7])[CH3:8])([CH3:32])[CH3:33])[cH:31][cH:30][cH:29]1)[c:16]1[cH:17][cH:18][c:19]([C:20](=[O:21])[N:22]([CH2:23][CH3:24])[CH2:25][CH3:26])[cH:27][cH:28]1

参加物

反応物 3

HCID 6344Dichloromethane

HCID 24386Thionyl Chloride

HCID 223500144-((3-((Tert-butyldimethylsilyl)oxy)phenyl)(hydroxy)methyl)-N,N-diethylbenzamide

生成物 1

HCID 223500364-(3-(tert-butyldimethylsilyloxy)-alpha-chlorobenzyl)-N,N-diethylbenzamide

出典と根拠

ORDレコード: ord-74469c2f98174519a11b3220e97dbe99
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (4/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…