Nickel Acetate → HCID 178435672、化合物

HRID 21497

反応式

HRID 21497 の反応式
C([O-])(=O)C.[Ni+2:5].C([O-])(=O)C.[CH2:10]([C:12]1[C:32]2[N:33]=[C:14]([CH:15]=[C:16]3[NH:43][C:19](=[CH:20][C:21]4[C:22]([CH2:41][CH3:42])=[C:23]([CH2:39][CH3:40])[C:24]([N:38]=4)=[CH:25][C:26]4[NH:30][C:29]([CH:31]=2)=[C:28]([CH2:34][CH3:35])[C:27]=4[CH2:36][CH3:37])[C:18]([CH2:44][CH3:45])=[C:17]3[CH2:46][CH3:47])[C:13]=1[CH2:48][CH3:49])[CH3:11]>>[Ni:5].[CH2:39]([C:23]1[C:24]2[N:38]=[C:21]([CH:20]=[C:19]3[NH:43][C:16](=[CH:15][C:14]4[C:13]([CH2:48][CH3:49])=[C:12]([CH2:10][CH3:11])[C:32]([N:33]=4)=[CH:31][C:29]4[NH:30][C:26]([CH:25]=2)=[C:27]([CH2:36][CH3:37])[C:28]=4[CH2:34][CH3:35])[C:17]([CH2:46][CH3:47])=[C:18]3[CH2:44][CH3:45])[C:22]=1[CH2:41][CH3:42])[CH3:40]

参加物

3

反応物 2

HCID 9756Nickel AcetateHCID 135742508Octaethyl-porphyrin

生成物 1

HCID 178435672HCID 178435672、化合物

実験手順

The nickel acetate is added to the octaethylporphyrin solution; the mixture which results is refluxed for about 24 hours until the electronic spectrum of the reaction mixture indicates that chelation is complete. The reaction mixture is then concentrated to 7 mL and allowed to cool to room temperature of about 22°. Product which precipitates is recovered by filtration, dissolved in a mixed solvent composed of 5 mL dichloromethane and 2 mL methanol, and recrystallized, yielding Ni octaethylporphyrin.

後処理

  1. customthe mixture which results
  2. temperatureis refluxed for about 24 hours until the electronic spectrum of the reaction mixture
  3. concentrationThe reaction mixture is then concentrated to 7 mL
  4. customProduct which precipitates
  5. filtrationis recovered by filtration
  6. dissolutiondissolved in a mixed solvent
  7. customrecrystallized

出典と根拠

ORDレコード
ord-813b69f14299474f9736d8b2058a4e23
出典データセット
uspto-grants-1995_06
特許番号
US05424305

関連ノート

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