Methyl iodide → Methyl 3-bromo-5-methoxybenzoate

反応式

[Br:1][C:2]1[CH:3]=[C:4]([CH:9]=[C:10]([OH:12])[CH:11]=1)[C:5]([O:7][CH3:8])=[O:6].[CH3:13]I>>[Br:1][C:2]1[CH:3]=[C:4]([CH:9]=[C:10]([O:12][CH3:13])[CH:11]=1)[C:5]([O:7][CH3:8])=[O:6]

参加物

反応物 2

HCID 6328Methyl iodide

HCID 53216607Methyl 3-bromo-5-hydroxybenzoate

生成物 1

HCID 15618226Methyl 3-bromo-5-methoxybenzoate

実験手順

Methyl 3-bromo-5-hydroxybenzoate (O6.032; 2.52 g) was alkylated with methyl iodide and worked up analogously to the conditions of O5.043. 2.5 g of the title compound were obtained.

出典と根拠

ORDレコード: ord-6d021308f0254f99845c3338ea80401d
出典データセット: uspto-grants-2012_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08198272B2

反応ノート

読み込み中…