Oxalyl chloride → HCID 22452672、化合物

HRID 2185892ノート

反応式

HRID 2185892 の反応式
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:13]([OH:15])=O)[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][C:11]=2[CH:12]=1.C(Cl)(=O)C([Cl:19])=O>C(Cl)Cl.CN(C=O)C>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([C:13]([Cl:19])=[O:15])[C:6]2[CH2:7][CH2:8][CH2:9][CH2:10][C:11]=2[CH:12]=1

参加物

5

反応物 2

HCID 65578Oxalyl chlorideHCID 22452645HCID 22452645、化合物

生成物 1

HCID 22452672HCID 22452672、化合物

試薬・触媒・溶媒 2

HCID 6228Dimethylformamide触媒HCID 6344Dichloromethane溶媒

実験手順

To a solution of 3-methoxy-5,6,7,8-tetrahydro-1-naphthalenecarboxylic acid (0.20 g, 0.97 mmol) in DCM (5 mL) was added oxalyl chloride (0.11 mL, 1.21 mmol) and 1 drop of DMF. The mixture was stirred at room temperature for 2 h. The solvent was removed in vacuo and 3-methoxy-5,6,7,8-tetrahydro-1-naphthalenecarbonyl chloride was used without purification.

後処理

  1. customThe solvent was removed in vacuo and 3-methoxy-5,6,7,8-tetrahydro-1-naphthalenecarbonyl chloride
  2. customwas used without purification

出典と根拠

ORDレコード
ord-de0db4e5718c4fb7b41a5a6b641bc610
出典データセット
uspto-grants-2002_06
特許番号
US06403601B1

反応ノート

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