((2-((6-Bromohexyl)oxy)ethoxy)methyl)benzene → 2-[(6-Bromohexyl)oxy]ethanol
反応式
[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:8][CH2:9][CH2:10][O:11]CC1C=CC=CC=1>CCOC(C)=O.CCO.[Pd]>[Br:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][O:8][CH2:9][CH2:10][OH:11]参加物
5
実験手順
A solution of [(2-[(6-bromohexyl)oxy]ethoxy)methyl]benzene (1.5 g) in EtOAc (20 ml) and EtOH (20 ml) was hydrogenated over 10% palladium on carbon (200 mg). After 2 h the mixture was filtered through celite and the filtrate evaporated in vacuo to give the title compound (1.05 g). TSP+ve 242 (MNH4)+, 244 (MNH4)+
後処理
- filtrationAfter 2 h the mixture was filtered through celite
- customthe filtrate evaporated in vacuo
出典と根拠
- ORDレコード
- ord-a91e8bb4e02c44509f0e49c1ab7a18ba
- 出典データセット
- uspto-grants-2012_06
- 特許番号
- US08198483B2
反応ノート
読み込み中…