4-Chlorotoluene → Tris(4-methylphenyl)sulfanium Chloride

反応式

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=O)=[CH:4][CH:3]=1.[Cl:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>>[Cl-:17].[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S+:8]([C:18]2[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1

参加物

反応物 2

HCID 78104-Chlorotoluene

HCID 15680p-Tolyl sulfoxide

生成物 1

HCID 5351245Tris(4-methylphenyl)sulfanium Chloride

実験手順

The intended compound was obtained by a similar manner to that in Synthesis Example 1 except that bis(4-methylphenyl)sulfoxide instead of diphenyl sulfoxide and 4-chlorotoluene instead of chlorobenzene were used, and the amount of water in the extraction was increased.

後処理

customThe intended compound was obtained by a similar manner to that
extractionthe amount of water in the extraction
temperaturewas increased

出典と根拠

ORDレコード: ord-6fd997a3705a4e11a6dd4f0f84b6db60
出典データセット: uspto-grants-2012_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08202677B2

反応ノート

読み込み中…

参加物