1,2-Dichloroethane → HCID 71525879、化合物

HRID 2205252

反応式

HRID 2205252 の反応式
C[C:2](C)(C(C)=C)[C:3](=[O:5])C.[NH:10]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:12]=[CH:11]1.N1[C:27]2[C:22](=[CH:23]C=C[CH:26]=2)[CH2:21]C=1.Cl[Sn](Cl)(Cl)Cl.Cl[CH2:34]CCl>>[CH3:34][C:27](=[C:22]([CH3:21])[CH3:23])[CH2:26][CH:11]1[CH2:12][C:13]2[C:18](=[CH:17][CH:16]=[CH:15][CH:14]=2)[N:10]1[C:3](=[O:5])[CH3:2]

参加物

6

反応物 5

HCID 111,2-DichloroethaneHCID 798IndoleHCID 24287Tin tetrachlorideHCID 30835603H-IndoleHCID 132625373,3,4-Trimethylpent-4-en-2-one

生成物 1

HCID 71525879HCID 71525879、化合物収率 58%

実験手順

Following the general procedure as described in Example 11, 3,3,4-trimethylpent-4-en-2-one (0.50 g, 3.96 mmol), 1H-indole (0.56 g, 4.75 mmol) which was in situ isomerized to 3H-indole, and SnCl4 (1.24 g, 4.75 mmol) in 1,2-dichloroethane (40 ml) were reacted to give the title product as a white solid (0.56 g, 58%).

後処理

  1. customwere reacted

出典と根拠

ORDレコード
ord-cfeb19e361a74c21b17c8dd50fedbe70
出典データセット
uspto-grants-2016_06
特許番号
US09371262B2

関連ノート

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