Benzylamine → 4-(Benzylamino)but-3-en-2-one

HRID 2207145ノート

反応式

HRID 2207145 の反応式
[CH2:1]([NH2:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.CO[CH:11]=[CH:12][C:13](=[O:15])[CH3:14]>C(Cl)(Cl)Cl>[CH2:1]([NH:8][CH:11]=[CH:12][C:13](=[O:15])[CH3:14])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

4

反応物 2

HCID 7504BenzylamineHCID 942973-Buten-2-one, 4-methoxy-

生成物 1

HCID 5214434-(Benzylamino)but-3-en-2-one収率 70%

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

A mixture of benzylamine (1.1 mL, 10 mmol) and 4-methoxybut-3-en-2-one (1 mL, 10 mmol) in chloroform (100 mL) was stirred at room temperature until complete conversion. Then, the solvent was evaporated to afford the desired product 30 in 70% yield which was used without additional purification.

後処理

  1. customThen, the solvent was evaporated

出典と根拠

ORDレコード
ord-6983509c973240aca8c91fe06bd0f612
出典データセット
uspto-grants-2016_06
特許番号
US09376387B2

反応ノート

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