HCID 54569294、化合物 → 3-Hexylaniline

HRID 2232414ノート

反応式

HRID 2232414 の反応式
[CH:1]([C:7]1[CH:8]=[C:9]([N+:13]([O-])=O)[CH:10]=[CH:11][CH:12]=1)=[CH:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>C(O)C.[Pd]>[CH2:1]([C:7]1[CH:8]=[C:9]([CH:10]=[CH:11][CH:12]=1)[NH2:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

参加物

5

反応物 2

HCID 54569294HCID 54569294、化合物HCID 178418361HCID 178418361、化合物

生成物 1

HCID 5722403-Hexylaniline収率 90.5%

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

The 3-(1-hexenyl)nitrobenzene (11.0 g, 0.054 m) was dissolved in absolute ethanol (500 ml), treated with 1.1 g of 10% palladium on charcoal catalyst and hydrogenated on a Parr apparatus at about 45 psi for 21/2 hours. Hydrogen uptake had ceased. The reaction mixture was filtered to remove catalyst, concentrated under vacuum, and then resulting oil purified by Kuglrohr distillation (BP 75°-85° C. at 0.05 mm Hg) to yield 3-hexylaniline (8.6 g, 90% yield) as a clear colorless oil.

後処理

  1. custom2 hours
  2. filtrationThe reaction mixture was filtered
  3. customto remove catalyst
  4. concentrationconcentrated under vacuum
  5. customresulting oil
  6. distillationpurified by Kuglrohr distillation (BP 75°-85° C. at 0.05 mm Hg)

出典と根拠

ORDレコード
ord-12db25c0d34f4f5da099e60db4a9b429
出典データセット
uspto-grants-1988_11
特許番号
US04788209

反応ノート

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