Trimethylsilylacetylene → HCID 68407374、化合物

HRID 2244462

反応式

HRID 2244462 の反応式
[N:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+:10]([O-:12])=[O:11])[CH:5]=1)=[N+:2]=[N-:3].[CH3:13][Si:14]([C:17]#[CH:18])([CH3:16])[CH3:15]>C1COCC1>[N+:10]([C:6]1[CH:5]=[C:4]([N:1]2[CH:18]=[C:17]([Si:14]([CH3:16])([CH3:15])[CH3:13])[N:3]=[N:2]2)[CH:9]=[CH:8][CH:7]=1)([O-:12])=[O:11]

参加物

4

反応物 2

HCID 66111TrimethylsilylacetyleneHCID 1509273-Nitrophenyl azide

生成物 1

HCID 68407374HCID 68407374、化合物

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

反応条件

温度
60 °C

実験手順

Azido-3-nitro-benzene (CAS:1516-59-2, 11.8 g, 72 mmol) were dissolved in 20 ml THF and 30 ml trimethylsilylacetylene. The reaction mixture was stirred at 60° C. for 3 days. The solvents were evaporated off and the title compound was obtained as a brown solid (16.9 g, 90%), mp 75-78° C.

後処理

  1. customThe solvents were evaporated off

出典と根拠

ORDレコード
ord-46412073a08d4be1babbe636a3492f41
出典データセット
uspto-grants-2010_03
特許番号
US07678815B2

関連ノート

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