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Ammonia → Ammonium acrylate acrylic acid

HRID 2245602
ノート
印刷プレビュー

反応式

HRID 2245602 の反応式
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[NH3:6]>O>[C:1]([O-:5])(=[O:4])[CH:2]=[CH2:3].[NH4+:6].[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3]
参加物実験手順後処理出典と根拠反応ノート

参加物

4

反応物 2

HCID 222AmmoniaHCID 6581Acrylic Acid

生成物 1

HCID 19048366Ammonium acrylate acrylic acid

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

In 52.96 g of water, was dissolved 28.32 g of a reagent acrylic acid (guaranteed reagent grade manufactured by Wako Pure Chemical Industries, Ltd.). The resulting solution was cooled in an ice bath and slowly mixed with 18.35 g of a 25% by weight aqueous ammonia solution under stirring while keeping the mixture at a temperature of 30° C. or lower to obtain a 40% by weight aqueous ammonium acrylate/acrylic acid=70/30 solution. The aqueous ammonium acrylate/acrylic acid=70/30 solution in an amount of 90 g was brought to 10° C. and purged with nitrogen for 30 minutes, followed by addition of 0.72 g of ammonium carbonate and 0.147 g of triallylamine. To the resulting solution, were added as an initiator 0.1387 g of ammonium persulfate, 0.0322 g of a 30% by weight aqueous hydrogen peroxide solution, and 0.0016 g of L-ascorbic acid. Polymerization was performed for one hour to obtain a polymer, which was then crushed and dried at 150° C. for one hours in an inert oven with a nitrogen atmosphere. After drying, the polymer was further dried at 170° C. for 30 minutes in an inert oven with a nitrogen atmosphere. The resin obtained as described above was named as a comparative water-absorbing resin (3). The results of measurement of water absorption of the comparative water-absorbing resin (3) are shown in Table 2.

後処理

  1. temperatureThe resulting solution was cooled in an ice bath
  2. customat a temperature of 30° C.

出典と根拠

ORDレコード
ord-7b71e16f1efb489f86287d0e910148ca
出典データセット
uspto-grants-2010_03
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07683150B2

反応ノート

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