Diethyl Ether → Silver alpha-methylacetoacetate
反応式
N(CCO)CCO.CCOCC.[CH3:13][CH:14]([C:18]([CH3:20])=[O:19])[C:15]([OH:17])=[O:16].[N+]([O-])([O-])=O.[Ag+:25]>O>[CH3:13][CH:14]([C:18]([CH3:20])=[O:19])[C:15]([O-:17])=[O:16].[Ag+:25]参加物
6
実験手順
Diethanolamine (4.4 g) was dissolved in water (5 mL), and this solution was added to the ether solution of α-methylacetoacetic acid while cooling with ice. A solution of silver nitrate (6.8 g) dissolved in water (8 mL) was then added dropwise. The white precipitate that precipitated was filtered off, washed with ice water and then isopropanol, and then dried, yielding silver α-methylacetoacetate as a white precipitate (yield 4.78 g).
後処理
- temperaturewhile cooling with ice
- additionwas then added dropwise
- customThe white precipitate that precipitated
- filtrationwas filtered off
- washwashed with ice water
- dry with materialisopropanol, and then dried
出典と根拠
- ORDレコード
- ord-19d0923f799749d287926cd45ed8382b
- 出典データセット
- uspto-grants-2010_03
- 特許番号
- US07683195B2
反応ノート
読み込み中…