Chlorotrimethylsilane → Stannane, chlorotricyclohexyl-

HRID 2246795

反応式

HRID 2246795 の反応式
C[Si]([Cl:5])(C)C.[OH-].[CH:7]1([Sn+:13]([CH:20]2[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21]2)[CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8]1>>[CH:20]1([Sn:13]([Cl:5])([CH:7]2[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12]2)[CH:14]2[CH2:19][CH2:18][CH2:17][CH2:16][CH2:15]2)[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25]1

参加物

3

反応物 2

HCID 6397ChlorotrimethylsilaneHCID 9864905Cyhexatin

生成物 1

HCID 76539Stannane, chlorotricyclohexyl-

実験手順

In a 500 mL three-necked flask, trimethylsilyl chloride (170 g, 109 mmol) was added to tricyclohexyltin hydroxide (80 g, 133 mmol) and heated at reflux during 18 hours. After distillation of trimethylsilyl chloride in excess and hexamethyldisiloxane under reduced pressure, the crude product was recrystallized in petroleum ether. White needles were obtained (39.82 g, 79.6 mmol).

後処理

  1. temperatureheated
  2. temperatureat reflux during 18 hours
  3. distillationAfter distillation of trimethylsilyl chloride in excess and hexamethyldisiloxane under reduced pressure
  4. customthe crude product was recrystallized in petroleum ether
  5. customWhite needles were obtained (39.82 g, 79.6 mmol)

出典と根拠

ORDレコード
ord-188e8eb6b60a451ca46c1ccd7ff9703f
出典データセット
uspto-grants-2010_03
特許番号
US07687581B2

関連ノート

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