Sodium (2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxohexyl phosphate → Fructose 6-phosphate

HRID 224742

反応式

HRID 224742 の反応式
[P:1]([O:5][CH2:6][C@@H:7]([OH:16])[C@@H:8]([OH:15])[C@H:9]([OH:14])[C:10](=[O:13])[CH2:11][OH:12])([O-:4])([O-:3])=[O:2].[Na+].[Na+]>O>[P:1]([O:5][CH2:6][C@@H:7]([OH:16])[C@@H:8]([OH:15])[C@H:9]([OH:14])[C:10](=[O:13])[CH2:11][OH:12])([OH:3])([OH:4])=[O:2]

参加物

3

反応物 1

HCID 22812950Sodium (2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxohexyl phosphate

生成物 1

HCID 69507Fructose 6-phosphate収率 93.5%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To 18.5 ml of 0.67 M cis-[Pt(NH3)2 (H2O)2 ](NO3)2, 4.5 grams of disodium D-fructose-6-phosphate were added. The solution was stoppered with a porous plug and stirred for 49 days. At the end of that time, a blue, water-insoluble precipitate had formed. It was collected, and then washed by alternate centrifugation and resuspension. The precipitate was vacuum dried to yield 3.6 grams of the above-identified complex.

後処理

  1. customIt was collected
  2. washwashed by alternate centrifugation and resuspension
  3. customdried

出典と根拠

ORDレコード
ord-3b57e06bcae3498eb36afe5a8b96656f
出典データセット
uspto-grants-1980_11
特許番号
US04234499

関連ノート

読み込み中…