Water → HCID 86747077、化合物

HRID 2253855ノート

反応式

HRID 2253855 の反応式
[CH:1]1[C:13]2[CH2:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[Li].[CH3:15][C:16]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)=[C:17]1[CH:21]=[CH:20][CH:19]=[CH:18]1.O>O1CCCC1.[Cl-].[Cl-].C1(C(=[Hf+2](C2C3C=CC=CC=3C3C2=CC=CC=3)C2C=CC=C2)C)C=CC=CC=1>[CH:17]1([C:16]2[CH:15]=[CH:25][CH:26]=[CH:27][C:22]=2[CH2:23][CH2:24][CH:12]2[C:11]3[CH:10]=[CH:9][CH:8]=[CH:7][C:6]=3[C:5]3[C:13]2=[CH:1][CH:2]=[CH:3][CH:4]=3)[CH2:18][CH2:19][CH:20]=[CH:21]1

参加物

6

反応物 3

HCID 962WaterHCID 5928226-Methyl-6-phenylfulveneHCID 69882698Lithium Fluorene

生成物 1

HCID 86747077HCID 86747077、化合物収率 84.2%

試薬・触媒・溶媒 2

HCID 178435949HCID 178435949、化合物触媒HCID 8028Tetrahydrofuran溶媒2 回

実験手順

(Phenyl(methyl)methylene)(9-fluorenyl)(cyclopentadienyl)hafnium dichloride ##STR12## A solution of 67.8 mmol of lithium-fluorene in 50 cm3 of tetrahydrofuran was added to a solution of 11.4 g (67.8 mmol) of 6-methyl-6-phenyl-fulvene in 40 cm3 of tetrahydrofuran at room temperature. After the mixture had been stirred at room temperature for 2 hours, 60 cm3 of water were added. The substance obtained after this addition was filtered off with suction, washed with diethyl ether and dried under an oil pump vacuum. 19.1 g (84.2%) of 2,2-cyclopentadienyl(9-fluorenyl)ethylbenzene were obtained (correct elemental analyses; 1H-NMR spectrum).

後処理

  1. customThe substance obtained
  2. additionafter this addition
  3. filtrationwas filtered off with suction
  4. washwashed with diethyl ether
  5. customdried under an oil pump vacuum

出典と根拠

ORDレコード
ord-21c3ed3ecbb449428f57aa043484a7b0
出典データセット
uspto-grants-1993_08
特許番号
US05232993

反応ノート

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