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7-Chloro-2-methylquinoline → Dimethyl 5-(3-(2-(7-chloroquinolin-2-yl)ethenyl)phenyl)-4,6-dithianonanedioate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 7-Chloro-2-methylquinoline | HCID 138395 | — |
| 反応物 | Dimethyl 3,3'-(((3-formylphenyl)methylene)bis(sulfanediyl))dipropanoate | HCID 10021188 | — |
| 溶媒 | Acetic Anhydride | HCID 7918 | — |
| 生成物 | Dimethyl 5-(3-(2-(7-chloroquinolin-2-yl)ethenyl)phenyl)-4,6-dithianonanedioate | HCID 53731421 | — |
反応手順
A solution of aldehyde (Step 1) (5.2 g) and 7-chloroquinaldine were heated in 45 ml acetic anhydride for 48 hours. The reaction mixture was evaporated. Flash chromatography of the residue using 5% ethylacetate in hexane afforded the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05428171 |
| 出典データセット | uspto-grants-1995_06 |
| ORD ID | ord-cfa2eb7e011a42859db8e0347809ca74 |
| 出典メモ | uspto-grants-1995_06 |