Potassium Hydroxide → HCID 15825476、化合物

HRID 2260094

反応式

HRID 2260094 の反応式
[OH:1][CH:2]([CH2:21][OH:22])[CH2:3][NH:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20].[OH-].[K+].[OH:25][CH:26]([CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44])[C:27]([O:29]C)=O>>[OH:1][CH:2]([CH2:21][OH:22])[CH2:3][N:4]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])[C:27](=[O:29])[CH:26]([OH:25])[CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH3:44]

参加物

4

反応物 3

HCID 14797Potassium HydroxideHCID 1110073-(Hexadecylamino)propane-1,2-diolHCID 543716Methyl 2-hydroxyhexadecanoate

生成物 1

HCID 15825476HCID 15825476、化合物

実験手順

N-(2,3-dihydroxypropyl)-N-hexadecylamine (1.0 g, 0.0032 mole) and potassium hydroxide (0.01 g, 0.18 mmole) were heated to 85° C. under vacuum and methyl 2-hydroxyhexadecanoate (0.907 g, 0.0032 mole) was heated and added dropwise to the reaction. The reaction was heated under vacuum for 6 hours. A waxy off-white solid was obtained (crude yield=1.79 g). The waxy solid was recrystalized from hot hexane (yield=0.94 g).

後処理

  1. temperaturewas heated
  2. additionadded dropwise to the reaction
  3. temperatureThe reaction was heated under vacuum for 6 hours
  4. customA waxy off-white solid was obtained (crude yield=1.79 g)
  5. customThe waxy solid was recrystalized from hot hexane (yield=0.94 g)

出典と根拠

ORDレコード
ord-b95a455865cc49fc8505d782444943a7
出典データセット
uspto-grants-1995_12
特許番号
US05476671

関連ノート

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