Thionyl Chloride → Sulfinylperfluorooctaneamide

HRID 227366ノート

反応式

HRID 227366 の反応式
[S:1](Cl)(Cl)=[O:2].C[Si](C)(C)[N:7]([Si](C)(C)C)[C:8](=[O:31])[C:9]([F:30])([F:29])[C:10]([F:28])([F:27])[C:11]([F:26])([F:25])[C:12]([F:24])([F:23])[C:13]([F:22])([F:21])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16]>>[S:1](=[N:7][C:8](=[O:31])[C:9]([F:29])([F:30])[C:10]([F:27])([F:28])[C:11]([F:25])([F:26])[C:12]([F:23])([F:24])[C:13]([F:21])([F:22])[C:14]([F:20])([F:19])[C:15]([F:18])([F:17])[F:16])=[O:2]

参加物

3

反応物 2

HCID 24386Thionyl ChlorideHCID 86615112N,N-bis(trimethylsilyl)perfluorooctaneamide

生成物 1

HCID 23161206Sulfinylperfluorooctaneamide

実験手順

Next, thionyl chloride (SOCl2) 2.4 g was added gradually to N,N-bis(trimethylsilyl)perfluorooctaneamide 12 g in the dry nitrogen atmosphere, which was allowed to react for two hours while being stirred. Then this was distilled and thereby sulfinylperfluorooctaneamide was obtained.

後処理

  1. customto react for two hours
  2. distillationThen this was distilled

出典と根拠

ORDレコード
ord-780d5624590a4ce0802a7cc83eceee8a
出典データセット
uspto-grants-2009_07
特許番号
US07560301B2

反応ノート

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