Methyl iodide → 6-Methoxy-1,1-dimethyl-3,4-dihydronaphthalen-2-one

反応式

CO[C:3]1[CH:12]=[C:11]2[C:6]([CH2:7][CH2:8][C:9](=[O:15])[C:10]2([CH3:14])[CH3:13])=[CH:5][CH:4]=1.[CH3:16][O:17]C1C=C2C(=CC=1)CC(=O)CC2.IC>>[CH3:16][O:17][C:4]1[CH:5]=[C:6]2[C:11](=[CH:12][CH:3]=1)[C:10]([CH3:13])([CH3:14])[C:9](=[O:15])[CH2:8][CH2:7]2

参加物

反応物 3

HCID 6328Methyl iodide

HCID 755826-Methoxy-1,2,3,4-tetrahydronaphthalen-2-one

HCID 130110077-Methoxy-1,1-dimethyl-3,4-dihydronaphthalen-2(1H)-one

生成物 1

HCID 125619446-Methoxy-1,1-dimethyl-3,4-dihydronaphthalen-2-one

実験手順

Under the same conditions as the method for synthesizing Compound A2, the title compound was prepared from 6-methoxy-3,4-dihydro-1H-naphthalen-2-one and iodomethane.

出典と根拠

ORDレコード: ord-29bbd07bcfda46bfacb8355e1205aa64
出典データセット: uspto-grants-2015_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US09126931B2

反応ノート

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