関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Bromobenzene | HCID 7961 | — |
| 反応物 | Dimethylacetamide | HCID 31374 | — |
| 反応物 | Hydrogenated cardanol | HCID 68146 | — |
| 反応物 | Potassium | HCID 5462222 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 1-Pentadecyl-3-phenoxybenzene | HCID 17747909 | — |
反応手順
Into the round bottom flask containing potassium salt of 3-pentadecyl phenol is added bromobenzene followed by Cu powder and in a solvent, DMAc (dimethyl acetamide). The reaction mixture is heated at 150° C. for 6 h. After completion of the reaction, the obtained dark colored reaction mixture is poured into water and the Cu salts are removed by filtration. The filtrate is extracted in a solvent, washed with water and dried, purified to obtain arylated product, 1-pentadecyl-3-phenoxybenzene.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US09133089B2 |
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| 出典データセット | uspto-grants-2015_09 |
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| ORD ID | ord-098d7520d0d44e888b6a85333b30fb9f |
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| 出典メモ | uspto-grants-2015_09 |
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