59177-46-7 → Benzamide

HRID 2282781ノート

反応式

HRID 2282781 の反応式
[H][H].S[C:4]1[CH:12]=[CH:11][C:7]([C:8]([NH2:10])=[O:9])=[CH:6][CH:5]=1>CO.[Au]>[C:8]([NH2:10])(=[O:9])[C:7]1[CH:11]=[CH:12][CH:4]=[CH:5][CH:6]=1

参加物

5

反応物 2

HCID 2235161259177-46-7HCID 178418361HCID 178418361、化合物

生成物 1

HCID 2331Benzamide

試薬・触媒・溶媒 2

HCID 23985Gold触媒HCID 887Methanol溶媒

実験手順

Gold substrates were annealed in a hydrogen flame to get rid of contamination and form well ordered Au surfaces. 4-Mercaptobenzamide prepared according to Example 4 was dissolved (1 mM) in methanol and degassed using argon to avoid oxidation of thiols. The insulated tips treated substrates were immersed in this solution for >2 hours. This resulted in the formation of monolayers of benzamide on the surface. Extended functionalization times degraded insulation on the probes so treatment of probes was limited to 2 h. Functionalization of gold substrates was carried out for up to 20 hours.

後処理

  1. temperatureflame
  2. customto get rid of contamination
  3. customform well ordered Au surfaces
  4. customdegassed
  5. additionThe insulated tips treated substrates
  6. waitwere immersed in this solution for >2 hours

出典と根拠

ORDレコード
ord-9806d765b84c46838e689ae673bf153b
出典データセット
uspto-grants-2015_09
特許番号
US09140682B2

反応ノート

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