Hydrogen Peroxide → HCID 12951084、化合物
反応式
FC(F)(F)C([O:5][C:6](=[O:11])[C:7]([F:10])([F:9])[F:8])=O.OO.[F:16][C:17]([F:47])([C:43]([F:46])([F:45])[F:44])[C:18]([F:42])([F:41])[C:19]([F:40])([F:39])[C:20]([F:38])([F:37])[C:21]([F:36])([F:35])[C:22]([F:34])([F:33])[C:23]([F:32])([F:31])[C:24]([F:30])([F:29])[C:25]([I:28])([F:27])[F:26]>FC(F)(F)C(O)=O>[F:8][C:7]([F:10])([F:9])[C:6]([O:11][I:28]([O:5][C:6](=[O:11])[C:7]([F:8])([F:9])[F:10])[C:25]([F:27])([F:26])[C:24]([F:30])([F:29])[C:23]([F:32])([F:31])[C:22]([F:34])([F:33])[C:21]([F:36])([F:35])[C:20]([F:37])([F:38])[C:19]([F:40])([F:39])[C:18]([F:41])([F:42])[C:17]([F:47])([F:16])[C:43]([F:44])([F:45])[F:46])=[O:5]参加物
5
実験手順
To a mixture of 10.6 ml (75.2 mmols) of trifluoroacetic anhydride and 30 ml of trifluoroacetic acid was added dropwise 1.36 ml of a 35% aqueous hydrogen peroxide solution (H2O2, 15.7 mmols and H2O, 55 mmols) in an ice bath. After completion of addition, the mixture was stirred for 1.5 hour and 5.0 g (7.7 mmols) of heneicosafluoro-n-decyl iodide was added thereto, followed by allowing the mixture to react at 0° to 5° C. for 24 hours. The solvent was then distilled off to obtain 6.3 g (94% yield) of di(trifluoroacetoxy)iodoheneicosafluoro-n-decane as white fluffy crystals.