Methyl triflate → HCID 15476282、化合物

HRID 2288572ノート

反応式

HRID 2288572 の反応式
[CH:1]1[C:14]2[C:5](=[N:6][C:7]3[C:12]([C:13]=2[C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[O:24](C)[S:25]([C:28]([F:31])([F:30])[F:29])(=[O:27])=[O:26]>C(Cl)Cl>[F:29][C:28]([F:31])([F:30])[S:25]([O-:27])(=[O:26])=[O:24].[CH3:28][N+:6]1[C:5]2[C:14](=[CH:1][CH:2]=[CH:3][CH:4]=2)[C:13]([C:15]([O:17][C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)=[O:16])=[C:12]2[C:7]=1[CH:8]=[CH:9][CH:10]=[CH:11]2

参加物

4

反応物 2

HCID 9526Methyl triflateHCID 517916Phenyl acridine-9-carboxylate

生成物 1

HCID 15476282HCID 15476282、化合物

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

Phenyl acridine-9-carboxylate (530 mg, 1.7 mmol) was dissolved in CH2Cl2 (5 mL) under argon and methyl triflate (1 mL, 8.8 mmol) was added. The solution was stirred overnight at room temperature to yield a thick yellow precipitate. This precipitate was filtered, washed with ether and dried to obtain the product as yellow crystals. 1H NMR (acetone-d6) δ 5.22 (s, 3H), 7.47-7.71 (m, 5H), 8.23-9.07 (m, 8H).

後処理

  1. customto yield a thick yellow precipitate
  2. filtrationThis precipitate was filtered
  3. washwashed with ether
  4. customdried

出典と根拠

ORDレコード
ord-ccd31068837e4f0483912c6297c5bf4a
出典データセット
uspto-grants-2000_07
特許番号
US06090571

反応ノート

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