Methanol → Quinacridone

HRID 2298701

反応式

HRID 2298701 の反応式
[NH:1]([C:8]1[CH:16]=[C:15]([C:17](O)=[O:18])[C:14]([NH:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[CH:13][C:9]=1[C:10](O)=[O:11])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.COC1C=CC(NC2C=C(C(O)=O)C(NC3C=CC(OC)=CC=3)=CC=2C(O)=O)=CC=1.CO>O>[CH:24]1[CH:25]=[C:26]2[C:17]([C:15]3[C:14]([NH:20][C:21]2=[CH:22][CH:23]=1)=[CH:13][C:9]1[C:10]([C:7]2[C:2]([NH:1][C:8]=1[CH:16]=3)=[CH:3][CH:4]=[CH:5][CH:6]=2)=[O:11])=[O:18]

参加物

5

反応物 3

HCID 887MethanolHCID 823512,5-Dianilinoterephthalic acidHCID 30848371,4-Benzenedicarboxylic acid, 2,5-bis[(4-methoxyphenyl)amino]-

生成物 1

HCID 13976Quinacridone

試薬・触媒・溶媒 1

HCID 962Water溶媒

反応条件

温度
130 °C

実験手順

A mixture (one part) of 2,5-dianilino-terephthalic acid (80 wt. %) and 2,5-dianisidino-terephthalic acid (20 wt. %) was dissolved in polyphosphoric acid (6.14 parts at 118.5%). The solution, already at 110° C., was heated to 130° C. for 3 hours, cooled to 100° C. and diluted to a fluid mass with water (0.5 parts). The solution was drowned into methanol (11.6 parts) and heated at 120° C. for 4 hours. A very bluish, transparent quinacridone pigment was obtained.

後処理

  1. temperaturecooled to 100° C.
  2. temperatureheated at 120° C. for 4 hours

出典と根拠

ORDレコード
ord-5be680ccc1ac465b8370b7b1b079841e
出典データセット
uspto-grants-2002_12
特許番号
US06494949B2

関連ノート

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