Butyl iodide → HCID 17902130、化合物

反応式

[N+:1]([C:4]1[CH:5]=[C:6]2[C:10](=[CH:11][CH:12]=1)[N:9]=[C:8]([CH3:13])[C:7]2([CH3:15])[CH3:14])([O-:3])=[O:2].[I:16][CH2:17][CH2:18][CH2:19][CH3:20]>>[I-:16].[CH2:17]([N+:9]1[C:10]2[C:6](=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:12][CH:11]=2)[C:7]([CH3:15])([CH3:14])[C:8]=1[CH3:13])[CH2:18][CH2:19][CH3:20]

参加物

反応物 2

HCID 10962Butyl iodide

HCID 975513H-Indole, 2,3,3-trimethyl-5-nitro-

生成物 1

HCID 17902130HCID 17902130、化合物

実験手順

5-Nitro-2,3,3-trimethylindole (250 mg, 1.22 mmol) and iodobutane (10 ml, 16.17 g, 87.87 mmol) were mixed and heated to reflux for 16hrs. The solvent was removed and the impure material stored at−20° C. for use in later reactions.

後処理

temperatureheated
temperatureto reflux for 16hrs
customThe solvent was removed
custom20° C.

出典と根拠

ORDレコード: ord-0bfeec58765445f6a35d1b465bfbc39c
出典データセット: uspto-grants-2004_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06828116B1

反応ノート

読み込み中…

参加物