1-Ethynyl-2,4-dimethylbenzene → HCID 86593393、化合物
反応式
[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1[C:9]#[CH:10].[CH3:11][C:12]1[CH:19]=[C:18]([CH3:20])[CH:17]=[CH:16][C:13]=1[CH2:14][SH:15].[Na]>>[CH3:1][C:2]1[CH:7]=[C:6]([CH3:8])[CH:5]=[CH:4][C:3]=1/[CH:9]=[CH:10]\[CH:14]([S:15][CH:9](/[CH:10]=[CH:9]\[C:3]1[CH:4]=[CH:5][C:6]([CH3:8])=[CH:7][C:2]=1[CH3:1])[C:3]1[CH:4]=[CH:5][C:6]([CH3:8])=[CH:7][C:2]=1[CH3:1])[C:13]1[CH:16]=[CH:17][C:18]([CH3:20])=[CH:19][C:12]=1[CH3:11]参加物
4
実験手順
A solution of 2,4-dimethylphenylacetylene (0.02 mol) and 2,4-dimethylbenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) is subjected to the General Procedure to form (Z)-2,4-dimethylstyryl-2,4-dimethylbenzylsulfide. The title compound is obtained following oxidation of the sulfide, according to the General Procedure.
出典と根拠
- ORDレコード
- ord-6a35af2b87c345f085e0d8111b63d9de
- 出典データセット
- uspto-grants-2004_12