Chlorodimethylsilane → HCID 13529574、化合物
反応式
[CH2:1]([C:3]([CH2:9][CH3:10])=[C:4]([CH2:7][CH3:8])[CH2:5][CH3:6])[CH3:2].[CH3:11][SiH:12]([CH3:14])[Cl:13].[Al+3].[Cl-].[Cl-].[Cl-]>CCCCC>[CH2:1]([C:3]([Si:12]([CH3:14])([CH3:11])[Cl:13])([CH2:9][CH3:10])[CH:4]([CH2:7][CH3:8])[CH2:5][CH3:6])[CH3:2]参加物
5
実験手順
2.1 g of tetraethylethylene, 2 ml (18 mmol) of dimethylchlorosilane and 200 mg of AlCl3 are reacted according to Example 1. After 2 hours, the reaction mixture is diluted with pentane and the precipitate is filtered off. The pentane is stripped from the filtrate in vacuo and the residue is distilled. This gives 2.8 g (80 % of theory) of product as a colourless liquid. Boiling point= 75° -80° .C/0.195 mbar.
後処理
- filtrationthe precipitate is filtered off
- distillationthe residue is distilled
出典と根拠
- ORDレコード
- ord-f356331159264929b2f24717349deb22
- 出典データセット
- uspto-grants-1987_09
- 特許番号
- US04695643
反応ノート
読み込み中…