クロロジメチルシラン

Chlorodimethylsilane

HCID 66108CAS 1066-35-9

基本情報

標準SMILES
C[SiH](C)Cl
InChIKey
YGHUUVGIRWMJGE-UHFFFAOYSA-N
分子式
C2H7ClSi
平均分子量
94.61 g/mol
単同位体質量
94.00055443

概要

Dimethylchlorosilane appears as a colorless fuming liquid with a pungent, burning odor. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.

名称と識別子

優先名称
Chlorodimethylsilane
IUPAC
chloro(dimethyl)silane
現地名
クロロジメチルシラン
英語名
Chlorodimethylsilane
分子式
C2H7ClSi
分子量
94.62

名称と別名

dimethylsilyl chloridedimethylmonochlorosilaneRefChem:575834DTXCID807355213-912-01066-35-9ChlorodimethylhydrosilaneChlorodimethylsilaneDimethylchlorohydrosilaneDimethylchlorosilaneDimethylhydrosilyl chlorideDTXSID0027355
名称をさらに表示
クロロジメチルシランジメチルクロロシランジメチルシリルクロリドクロロ(ジメチル)シランDMCSDMSCCD5470CFS-359orodimethyL
Silane, chlorodimethyl-XR7E4F5838chloro(dimethyl)silaneDimethylsilylchloridechiorodimethylsilaneHSiMe2ClMe2SiHClSiHMe2Cl

データベース識別子

CAS
1066-35-9
PubChem CID
66108
DTXSID
DTXSID0027355
EC Number
213-912-0

物性

構造計算による物性

極性表面積
0 Ų
水素結合供与体数
0
水素結合受容体数
0
回転可能結合数
0
重原子数
4

実験および物理化学的性質

Chemical ClassesToxic Gases & Vapors -> Chlorosilanes
SpringerMaterials Properties29Si nuclear magnetic resonance spectrum
Density0.852 @25 °C
Boiling Point34.6 °C @760 [mm Hg]
Melting Point-111 °C
Vapor Pressure442.6 [mmHg]

物理化学的性質

融点
111 °C · −111 °C(lit.)
沸点
34.7 °C · 34.7 °C(lit.)
比重(密度)
0.852 g/mL · 0.852 g/mL at 25 °C(lit.)
蒸気密度
4 · 4 (vs air)
蒸気圧
8.56 psi · 8.56 psi ( 20 °C)
屈折率
20 · n20/D 1.383(lit.)

化学的性質

化学的特性Colorless clear liquid

安全と法規制

GHS分類

GHS Classification · 5 件

This chemical does not meet GHS hazard criteria for 0.2% (4 of 2413) of reports.

Danger

H224 (98.8%): Extremely flammable liquid and vapor [Danger Flammable liquids]

P210, P231+P232, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2413 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危険有害性情報

Regulatory Information · 4 件

Chemical: Silane, chlorodimethyl-

Silane, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 12-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14141

Chlorodimethylsilane: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelFlammable Liquid Corrosive
Fire HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Health HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Hazards Summary · 1 件

Reacts violently with water evolving heat and hydrogen chloride gas; Liquid and vapor highly corrosive to skin and respiratory tissue; [CAMEO] Reacts with water producing flammable gases that may ignite spontaneously; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]

Reactive GroupChlorosilanes

安全と保護具

Fire FightingExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
First AidExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Exposure Control and Personal Protection · 1 件

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

Nonfire Spill ResponseExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Isolation and EvacuationExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Protective Action Criteria (PAC) · 3 件

1.8 [ppm]

22 [ppm]

100 [ppm]

毒性情報

Adverse EffectsDermatotoxin - Skin burns.

安全データ

F
10-21
wgk
1
tsca
TSCA listed
ridadr
UN 2988 4.3/PG 1
hs_code
29310095
risk_code
11-34-12-35-20-14/15

化学と産業

用途と製造

UsesToxic Gas from Spilling Chemical in Water [Category: Other]
U.S. Production2023: 2,500,000 - <4,000,000 lb
Industry UsesMonomers
General Manufacturing Information · 2 件

All Other Basic Inorganic Chemical Manufacturing

Silane, chlorodimethyl-: ACTIVE

応用分野 · 3 件

用途ガスクロマトグラフ分析における試料の前処理剤(DMS化剤)。

使用Chlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides. Chlorodimethylsilane in combination with a tertiary amine such as triethylamine is another useful reagent for the synthesis of hydrodimethylsilyl ethers, especially for large scale preparations.

一般的な説明A colorless fuming liquid with a pungent, burning odor. Flash point -18°F. Boiling point 95°F. Density about 6.9 lb / gal. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.

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