基本情報
- 標準SMILES
C[SiH](C)Cl- InChIKey
YGHUUVGIRWMJGE-UHFFFAOYSA-N- 分子式
- C2H7ClSi
- 平均分子量
- 94.61 g/mol
- 単同位体質量
- 94.00055443
概要
Dimethylchlorosilane appears as a colorless fuming liquid with a pungent, burning odor. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.
名称と識別子
- 優先名称
- Chlorodimethylsilane
- IUPAC
- chloro(dimethyl)silane
- 現地名
- クロロジメチルシラン
- 英語名
- Chlorodimethylsilane
- 分子式
- C2H7ClSi
- 分子量
- 94.62
名称と別名
名称をさらに表示
データベース識別子
- CAS
1066-35-9- PubChem CID
- 66108
- DTXSID
DTXSID0027355- EC Number
- 213-912-0
物性
構造計算による物性
- 極性表面積
- 0 Ų
- 水素結合供与体数
- 0
- 水素結合受容体数
- 0
- 回転可能結合数
- 0
- 重原子数
- 4
- 形式電荷
- 0
- 複雑度
- 13.5
実験および物理化学的性質
Physical Description
Dimethylchlorosilane appears as a colorless fuming liquid with a pungent, burning odor. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.
Liquid
Colorless fuming liquid with a pungent, burning odor; Bp = 35 deg C; [CAMEO]
物理化学的性質
- 融点
- 111 °C · −111 °C(lit.)
- 沸点
- 34.7 °C · 34.7 °C(lit.)
- 比重(密度)
- 0.852 g/mL · 0.852 g/mL at 25 °C(lit.)
- 蒸気密度
- 4 · 4 (vs air)
- 蒸気圧
- 8.56 psi · 8.56 psi ( 20 °C)
- 屈折率
- 20 · n20/D 1.383(lit.)
- 闪点
- 20 °F · −20 °F
- 貯蔵温度
- 2 · 2-8°C
- 溶解性
- 有機溶剤と混和します。
- 外見
- 液体
- 色
- 無色透明
- 比重
- 0.868 · 0.868
- 爆発限界(explosive limit)
- 3 · 3.0-20.0%(V)
- 水溶解度
- 反応する
- BRN
- 1633434 · 1633434
- InChI
- 1S/C2H7ClSi/c1-4(2)3/h4H,1-2H3
- InChIKey
- YGHUUVGIRWMJGE-UHFFFAOYSA-N
- SMILES
- C[SiH](C)Cl
- CAS データベース
- 1066 · 1066-35-9(CAS DataBase Reference)
- NISTの化学物質情報
- Silane, chlorodimethyl-(1066-35-9)
- EPAの化学物質情報
- Silane, chlorodimethyl- (1066-35-9)
化学的性質
化学的特性Colorless clear liquid
安全と法規制
GHS分類
GHS Classification
This chemical does not meet GHS hazard criteria for 0.2% (4 of 2413) of reports.
Danger
H224 (98.8%): Extremely flammable liquid and vapor [Danger Flammable liquids]
P210, P231+P232, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 2413 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
危険有害性情報
Regulatory Information
Chemical: Silane, chlorodimethyl-
Silane, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 12-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14141
Chlorodimethylsilane: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Reacts violently with water evolving heat and hydrogen chloride gas; Liquid and vapor highly corrosive to skin and respiratory tissue; [CAMEO] Reacts with water producing flammable gases that may ignite spontaneously; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]
Reactivity Profile
Chlorosilanes, such as DIMETHYLCHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.
安全と保護具
Exposure Control and Personal Protection
TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].
Protective Action Criteria (PAC)
1.8 [ppm]
22 [ppm]
100 [ppm]
AEGLs Table
AEGL 1: Notable discomfort, irritation, or certain asymptomatic non-sensory effects. However, the effects are not disabling and are transient and reversible upon cessation of exposure (Unit: ppm)
1.8
1.8
1.8
1.8
1.8
毒性情報
安全データ
- F
- 10-21
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 2988 4.3/PG 1
- hs_code
- 29310095
- risk_code
- 11-34-12-35-20-14/15
- 化審法
- (2)-2041
- 消防法
- 危-4-特-I
- hazard_code
- F,C,F+
- safety_code
- 16-26-36/37/39-45-9-43
- hazard_class
- 3
- packing_group
- I
- Hazard Classifications
- Acute Tox. 3 InhalationFlam. Liq. 1Skin Corr. 1AWater-react 3
- ストレージクラス
- 4.3 - Hazardous materials which set free flammable gases upon contact with water
化学と産業
用途と製造
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing
Silane, chlorodimethyl-: ACTIVE
応用分野
用途ガスクロマトグラフ分析における試料の前処理剤(DMS化剤)。
使用Chlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides. Chlorodimethylsilane in combination with a tertiary amine such as triethylamine is another useful reagent for the synthesis of hydrodimethylsilyl ethers, especially for large scale preparations.
一般的な説明A colorless fuming liquid with a pungent, burning odor. Flash point -18°F. Boiling point 95°F. Density about 6.9 lb / gal. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.
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