Samarium → Anthracene
反応式
[Sm].[CH:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([CH:14]=2)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.[Yb]>COCCOC>[CH:5]1[C:6]2[C:15](=[CH:14][C:13]3[C:8]([CH:7]=2)=[CH:9][CH:10]=[CH:11][CH:12]=3)[CH:2]=[CH:3][CH:4]=1参加物
4
実験手順
Example 1 is repeated, but with the use of 20 m.g atoms of samarium powder instead of ytterbium. Anthracene samarium (1/1) solvated with DME, is obtained as a purple compound with a substantially quantitative yield with respect to anthracene. The complex, treated with a water excess, gives dihydroanthracene with a quantitative yield.
出典と根拠
- ORDレコード
- ord-5448869b772e453abe847c556d786061
- 出典データセット
- uspto-grants-1989_07
- 特許番号
- US04845201
反応ノート
読み込み中…