Phenyl benzoate → Phenyl benzoate samarium

HRID 231207

反応式

HRID 231207 の反応式
[C:1]([O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Sm:16]>COCCOC>[C:1]([O:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1.[Sm:16]

参加物

4

反応物 2

HCID 7169Phenyl benzoateHCID 23951Samarium

生成物 1

HCID 86743198Phenyl benzoate samarium

試薬・触媒・溶媒 1

HCID 80711,2-Dimethoxyethane溶媒

実験手順

By reacting 0.85 mmole of phenyl benzoate in 6 ml of DME with 3.38 m atoms of samarium, in the conditions of example 9, a dark-brown compound (phenyl benzoate-samarium) has been obtained and treated as usually. Benzoate was quantitatively converted.

出典と根拠

ORDレコード
ord-286940d6c433467f9268cdc443fc3240
出典データセット
uspto-grants-1989_07
特許番号
US04845201

関連ノート

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