Trimethylamine → HCID 14498256、化合物

HRID 231273ノート

反応式

HRID 231273 の反応式
[CH3:1][O:2][CH:3]([CH2:16][O:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH:30]1[CH2:35][CH2:34][CH2:33][CH2:32][CH2:31]1)[CH2:4][S:5]([CH2:8][CH2:9][CH2:10][O:11][S:12]([CH3:15])(=[O:14])=[O:13])(=[O:7])=[O:6].[CH3:36][N:37]([CH3:39])[CH3:38]>C1(C)C=CC=CC=1>[S:12]([O-:14])(=[O:13])(=[O:11])[CH3:15].[CH:30]1([CH2:29][CH2:28][CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][O:17][CH2:16][CH:3]([O:2][CH3:1])[CH2:4][S:5]([CH2:8][CH2:9][CH2:10][N+:37]([CH3:39])([CH3:38])[CH3:36])(=[O:7])=[O:6])[CH2:35][CH2:34][CH2:33][CH2:32][CH2:31]1

参加物

4

反応物 2

HCID 1146TrimethylamineHCID 200348483-Mesyloxypropyl 2-methoxy-3-(12-cyclohexyldodecyloxy)propyl sulfone

生成物 1

HCID 14498256HCID 14498256、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

In 50 ml of toluene containing 10 g of trimethylamine is dissolved 5.4 g of 3-mesyloxypropyl 2-methoxy-3-(12-cyclohexyldodecyloxy)propyl sulfone, and the mixture is stirred at room temperature for 5 days. The reaction mixture is then concentrated to dryness and the residue is purified by silica gel column chromatography to obtain 3.17 g of the captioned compound.

後処理

  1. concentrationThe reaction mixture is then concentrated to dryness
  2. customthe residue is purified by silica gel column chromatography

出典と根拠

ORDレコード
ord-bf3981c375a8487e95b82749d95f8906
出典データセット
uspto-grants-1989_07
特許番号
US04845219

反応ノート

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