Ethanolamine → 2-(beta-Hydroxyethyl)amino-6-(beta-hydroxyethyl)amino-4-chloronitrobenzene

HRID 231374ノート

反応式

HRID 231374 の反応式
Cl[C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[C:4](Cl)[C:3]=1[N+:10]([O-:12])=[O:11].[CH2:13]([CH2:15][NH2:16])[OH:14]>>[Cl:8][C:6]1[CH:5]=[C:4]([NH:16][CH2:15][CH2:13][OH:14])[C:3]([N+:10]([O-:12])=[O:11])=[C:2]([NH:16][CH2:15][CH2:13][OH:14])[CH:7]=1

参加物

3

反応物 2

HCID 700EthanolamineHCID 292282,4,6-Trichloronitrobenzene

生成物 1

HCID 200710912-(beta-Hydroxyethyl)amino-6-(beta-hydroxyethyl)amino-4-chloronitrobenzene

実験手順

0.132 mole (30 g) of 2,4,6-trichloronitrobenzene is heated to 95° C. in 120 ml of ethanolamine. After 30 minutes, the reaction medium is poured into 240 g of an ice-water mixture. The product expected precipitates. It is drained, washed with water and then dried under vacuum in the presence of phosphorous pentoxide. After recrystallizing from absolute ethanol, it melts at 154° C.

後処理

  1. customThe product expected precipitates
  2. washwashed with water
  3. dry with materialdried under vacuum in the presence of phosphorous pentoxide
  4. customAfter recrystallizing from absolute ethanol, it melts at 154° C.

出典と根拠

ORDレコード
ord-0b6c28dde6634d2b8761689383ed485d
出典データセット
uspto-grants-1989_07
特許番号
US04845293

反応ノート

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