Nitric Acid → 1,5-Dichloro-2-methyl-4-nitrobenzene

HRID 231410

反応式

HRID 231410 の反応式
[N+:1]([O-:4])(O)=[O:2].[Cl:5][C:6]1[CH:11]=[C:10]([Cl:12])[CH:9]=[CH:8][C:7]=1[CH3:13]>O>[Cl:5][C:6]1[CH:11]=[C:10]([Cl:12])[C:9]([N+:1]([O-:4])=[O:2])=[CH:8][C:7]=1[CH3:13]

参加物

4

反応物 2

HCID 944Nitric AcidHCID 72542,4-Dichlorotoluene

生成物 1

HCID 2516791,5-Dichloro-2-methyl-4-nitrobenzene

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

To stirred fuming nitric acid (200 ml) at 0° C. was added slowly 2,4-dichlorotoluene (50 g, 0.3mole). Upon completion of addition, the reaction mixture was stirred for one hour, then was poured into water (100 ml). A yellow precipitate was collected by filtration to yield 62.0 g of 2,4-dichloro-5-nitrotoluene, m.p. 40°-44° C.

後処理

  1. additionUpon completion of addition
  2. filtrationA yellow precipitate was collected by filtration

出典と根拠

ORDレコード
ord-4f9b118a8e5a481c85728d2ae6153fcb
出典データセット
uspto-grants-1989_07
特許番号
US04846875

関連ノート

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