Benzoyl Peroxide → (2,4-Dichloro-5-nitrophenyl)methyl bromide

HRID 231411

反応式

HRID 231411 の反応式
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH3:12].[Br:13]N1C(=O)CCC1=O.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C(Cl)(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([N+:9]([O-:11])=[O:10])=[CH:4][C:3]=1[CH2:12][Br:13]

参加物

5

反応物 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2516791,5-Dichloro-2-methyl-4-nitrobenzene

生成物 1

HCID 14501785(2,4-Dichloro-5-nitrophenyl)methyl bromide

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

This compound was prepared in a manner similar to Example 1 Step F using 2,4-dichloro-5-nitrotoluene (62.0 g, 0.3 mole), N-bromosuccinimide (160.2 g, 0.9 mole), benzoyl peroxide (2.0 g) and carbon tetrachloride (500 ml) to yield (2,4-dichloro-5-nitrophenyl)methyl bromide. The NMR spectrum was consistent with the proposed structure.

後処理

  1. customThis compound was prepared in a manner similar to Example 1 Step F

出典と根拠

ORDレコード
ord-b2fd7d6809ae443fa2e3d2bbc9fa27eb
出典データセット
uspto-grants-1989_07
特許番号
US04846875

関連ノート

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