Acetic Acid → tert-Butyl 5-(tert-butyldiphenylsilanyloxy)-3-formylvalerate

反応式

[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][CH2:8][CH:9]([CH2:10][C:11](=[O:12])[O:13][C:14]([CH3:15])([CH3:16])[CH3:17])[C:18]([NH:19][CH2:20][O:21][CH3:22])=[O:23])([c:24]1[cH:25][cH:26][cH:27][cH:28][cH:29]1)[c:30]1[cH:31][cH:32][cH:33][cH:34][cH:35]1.[CH2:42]([Al+:43][CH2:44][CH:45]([CH3:46])[CH3:47])[CH:48]([CH3:49])[CH3:50].[CH3:51][C:52](=[O:53])[OH:54].[H-:41].[O:36]1[CH2:37][CH2:38][CH2:39][CH2:40]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][CH2:8][CH:9]([CH2:10][C:11](=[O:12])[O:13][C:14]([CH3:15])([CH3:16])[CH3:17])[CH:18]=[O:23])([c:24]1[cH:25][cH:26][cH:27][cH:28][cH:29]1)[c:30]1[cH:31][cH:32][cH:33][cH:34][cH:35]1