Ethyl benzoylacetate → 1-benzoyl-6-bromo-2,7-dihydro-3-methyl-2,7-dioxo-3H-dibenzo[f,ij]isoquinoline

反応式

[C:1]([CH2:9][C:10]([O:12]CC)=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:15][NH:16][C:17]1[C:30]2[C:29](=O)[C:28]3[C:23](=[CH:24][CH:25]=[CH:26][CH:27]=3)[C:22](=[O:32])[C:21]=2[C:20]([Br:33])=[CH:19][CH:18]=1>>[C:1]([C:9]1[C:10](=[O:12])[N:16]([CH3:15])[C:17]2[CH:18]=[CH:19][C:20]([Br:33])=[C:21]3[C:22](=[O:32])[C:23]4[CH:24]=[CH:25][CH:26]=[CH:27][C:28]=4[C:29]=1[C:30]=23)(=[O:8])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

参加物

反応物 2

HCID 7170Ethyl benzoylacetate

HCID 314189,10-Anthracenedione, 1-bromo-4-(methylamino)-

生成物 1

HCID 118585271-benzoyl-6-bromo-2,7-dihydro-3-methyl-2,7-dioxo-3H-dibenzo[f,ij]isoquinoline

実験手順

Ethyl benzoylacetate is reacted with 1-methylamino-4-bromoanthraquinone in a solvent to obtain 1-benzoyl-6-bromo-2,7-dihydro-3-methyl-2,7-dioxo-3H-dibenzo[f,ij]isoquinoline.

出典と根拠

ORDレコード: ord-cc29ec2117a1404fa261872c82b51c8f
出典データセット: uspto-grants-2005_02
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06852154B2

反応ノート

読み込み中…