Allyl bromide → HCID 10361612、化合物
反応式
[CH3:1][N:2]1[C@H:11]2[CH2:12][C:13]3[C:14](=[CH:15][C:16]([O:20][CH3:21])=[C:17]([OH:19])[CH:18]=3)[C:9]3[C:10]2=[C:5]([CH:6]=[C:7]([OH:24])[C:8]=3[O:22][CH3:23])[CH2:4][CH2:3]1.[CH2:25](Br)[CH:26]=[CH2:27]>>[CH3:1][N:2]([CH2:27][CH:26]=[CH2:25])[CH2:3][CH2:4][C:5]1[C:10]2[CH:11]=[CH:12][C:13]3[C:14]([C:9]=2[C:8]([O:22][CH3:23])=[C:7]([OH:24])[CH:6]=1)=[CH:15][C:16]([O:20][CH3:21])=[C:17]([OH:19])[CH:18]=3参加物
3
実験手順
1 g of boldine was dissolved in 30 ml of N,N-dimethylformamide(DMF), the mixture was reacted with 1.2 ml of allyl bromide at 100°-110° C. for 2 hours. The residue obtained after evaporation under reduced pressure was purified to give the pure compound (1) N-allylsecoboldine.
後処理
- customThe residue obtained
- customafter evaporation under reduced pressure
- customwas purified
出典と根拠
- ORDレコード
- ord-d17de981498644e28f737b6cd522b3ba
- 出典データセット
- uspto-grants-1997_01