Rhodium → Rhodium Tribenzylphosphine

HRID 2351265ノート

反応式

HRID 2351265 の反応式
[Rh:1].[CH2:2]([P:9]([CH2:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)[CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>CC(C(O)C(COC(C(C)C)=O)(C)C)C>[Rh:1].[CH2:17]([P:9]([CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1)[CH2:10][C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)[C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1

参加物

4

反応物 2

HCID 23948RhodiumHCID 82101Phosphine, tris(phenylmethyl)-

生成物 1

HCID 86743422Rhodium Tribenzylphosphine

試薬・触媒・溶媒 1

HCID 6490Texanol溶媒

反応条件

温度
125 °C

実験手順

A catalyst charge comprised of 31.25 mg of rhodium (as rhodium 2-ethylhexanoate) and varying amounts of tribenzylphosphine (as noted in Table 3) dissolved in 0.2 liter of Texanol® solvent was charged to the reactor system described above. The reactor was maintained at 125° C. and operated continuously for seven hours. The reaction was conducted according to the general procedure set forth above. Operating parameters and reaction results are set forth in Table 3.

後処理

  1. additionA catalyst charge
  2. additionwas charged to the reactor system
  3. customOperating parameters and reaction
  4. customresults

出典と根拠

ORDレコード
ord-10c543711fbd4d2286fad605ff01ec96
出典データセット
uspto-grants-1989_10
特許番号
US04873213

反応ノート

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