Veratrole → 3,4-Dimethoxyphenyltellurium trichloride

HRID 2352052ノート

反応式

HRID 2352052 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[O:9][CH3:10].[Te:11](Cl)([Cl:14])([Cl:13])[Cl:12]>C(Cl)(Cl)Cl>[CH3:1][O:2][C:3]1[CH:8]=[C:7]([Te:11]([Cl:14])([Cl:13])[Cl:12])[CH:6]=[CH:5][C:4]=1[O:9][CH3:10]

参加物

4

反応物 2

HCID 7043VeratroleHCID 61443Tellurium tetrachloride

生成物 1

HCID 124943393,4-Dimethoxyphenyltellurium trichloride

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

1,2-Dimethoxybenzene (veratrole, 13.8 g=0.1 mole) and tellurium tetrachloride (26.9 g=0.1 mole) were heated in chloroform (120 ml) for 2 hours under reflux and with stirring. After 30 minutes yellow crystals started to precipitate. The product (25.2 g, 67.9% of theory) was collected by filtration and dried in a vacuum oven, m.p. 162°-163° C. (dec. with gas evolution). The mass spectra were in agreement with that of the structural formula.

後処理

  1. temperatureunder reflux
  2. customto precipitate
  3. filtrationThe product (25.2 g, 67.9% of theory) was collected by filtration
  4. customdried in a vacuum oven, m.p. 162°-163° C. (dec. with gas evolution)

出典と根拠

ORDレコード
ord-a08e54a1169e4d3cb85d4d16b0cf70b0
出典データセット
uspto-grants-1989_10
特許番号
US04874866

反応ノート

読み込み中…