O-Methylhydroxylamine → HCID 19042150、化合物
反応式
[CH3:1][O:2][NH2:3].[N+:4](/[C:7](=[CH:9]/[CH3:10])/[CH3:8])([O-:6])=[O:5]>>[CH3:1][O:2][NH:3][CH:9]([CH3:10])[CH:7]([N+:4]([O-:6])=[O:5])[CH3:8]参加物
3
反応条件
- 温度
- 25 °C
実験手順
O-Methylhydroxylamine (176 mg, 3.75 mmol) was added to (E)-2-nitro-2-butene (303 mg, 3 mmol) and the resulting mixture was stirred at 25° C. for 10 minutes. Then, the product was isolated and purified by silica gel thin-layer chromatography (eluent: ethyl acetate/hexane=1/5). O-Methyl-N-(α-methyl-β-nitropropyl)hydroxylamine (mixture of diastereomers, yield: 95%)
後処理
- customThen, the product was isolated
- custompurified by silica gel thin-layer chromatography (eluent: ethyl acetate/hexane=1/5)
出典と根拠
- ORDレコード
- ord-480c772dc73f4d50b13bd070d6581f1b
- 出典データセット
- uspto-grants-1997_01
- 特許番号
- US05597940
反応ノート
読み込み中…