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1-Iodohexadecane → 1-Hexadecyl-2-methoxybenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Iodohexadecane | HCID 11007 | — |
| 反応物 | 2-Bromoanisole | HCID 11358 | — |
| 反応物 | Magnesium | HCID 5462224 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | 1-Hexadecyl-2-methoxybenzene | HCID 20218652 | 102% |
反応手順
To a refluxing solution of about 35.3 g of hexadecyl iodide in tetrahydrofuran was added a solution of about 37.4 g of bromoanisole and about 4.86 g of magnesium in tetrahydrofuran which had been refluxed for about 2 hours. An about 10 ml portion of about 0.1M lithium cupric chloride was added, the mixture was refluxed about 2 hours and stirred at room temperature for about 16 hours giving about 34 g of the desired reagent.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04640913 |
| 出典データセット | uspto-grants-1987_02 |
| ORD ID | ord-79e0827f7dc4487992b562bca3ef6639 |
| 出典メモ | uspto-grants-1987_02 |