2,2-Dimethylhexane → 2-Methylbuta-1,3-diene--2-methylprop-1-ene (1/1)

HRID 236382

反応式

HRID 236382 の反応式
[CH3:1][C:2](C)([CH3:7])[CH2:3][CH2:4]CC>C(Cl)(Cl)(Cl)Cl>[CH3:3][C:2]([CH3:7])=[CH2:1].[CH3:7][C:2]([CH:3]=[CH2:4])=[CH2:1]

参加物

3

反応物 1

HCID 115512,2-Dimethylhexane

生成物 1

HCID 627032-Methylbuta-1,3-diene--2-methylprop-1-ene (1/1)

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

反応条件

温度
75 °C

実験手順

A 3.5% solution of 10 g of poly(isobutylene-co-isoprene) was prepared in 96.5% of a 1:1 mixture of trimethylpentane and CCl4. The solution was purged with N2, heated to 75° C., 0.3 g of benzoyl peroxide was added, followed by 40 g of methylmethacrylate, added over a period of 1 hour. The polymerization was carried out for 16 hours with constant mechanical stirring. After cooling to room temperature, the cleaning procedure used was identical to that of Example 1.

後処理

  1. customThe solution was purged with N2
  2. addition0.3 g of benzoyl peroxide was added
  3. additionadded over a period of 1 hour
  4. temperatureAfter cooling to room temperature

出典と根拠

ORDレコード
ord-d951b2b78e8b4edf9165641b535f0515
出典データセット
uspto-grants-1987_02
特許番号
US04644041

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