Trimethylsilanol → Hexamethyldisiloxane

HRID 236426

反応式

HRID 236426 の反応式
[CH3:1][Si:2]([CH3:5])([CH3:4])[OH:3]>C(OCC)C>[CH3:1][Si:2]([O:3][Si:2]([CH3:5])([CH3:4])[CH3:1])([CH3:5])[CH3:4]

参加物

3

反応物 1

HCID 66110Trimethylsilanol

生成物 1

HCID 24764Hexamethyldisiloxane

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

This reaction proceeds slowly without diethylether but reacts faster at reflux temperatures. Trimethylsilanol is condensed during the HMDS distillation step to give HMDSO, which reacts as shown above.

後処理

  1. customreacts faster
  2. temperatureat reflux temperatures
  3. customcondensed
  4. distillationduring the HMDS distillation step

出典と根拠

ORDレコード
ord-5481fd3911d649d58cd82ef099a34174
出典データセット
uspto-grants-1987_02
特許番号
US04644076

関連ノート

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